賀婧+羅玲玲+楊超



摘要:以寧夏典型石灰性土壤為供試材料,通過吸附解吸試驗,探尋石灰性土壤對重金屬鉛的固持能力。結果表明,灰鈣土對重金屬鉛的平均吸附率為89.78%,風沙土對重金屬鉛的平均吸附率為80.29%,灰鈣土對重金屬鉛的吸附能力較強。兩種土壤中有機質對土壤吸附鉛的貢獻率(灰鈣土為11.96%,風沙土為7.87%)均小于碳酸鈣對土壤吸附鉛的貢獻率(灰鈣土為17.21%,風沙土為11.96%),與有機質相比,碳酸鈣對石灰性土壤吸附重金屬鉛的影響更大。
關鍵詞:碳酸鈣;土壤;固持;重金屬鉛
中圖分類號:X53 ? ? ? ?文獻標識碼:A ? ? ? ?文章編號:0439-8114(2015)23-5839-04
DOI:10.14088/j.cnki.issn0439-8114.2015.23.012
Immobilization Effect of Calcium Carbonate on Heavy Metallic Lead in Soil
HE Jing,LUO Ling-ling,YANG Chao
(School of Resource and Environment, Ningxia University, Yinchuan ?750021, China)
Abstract:Using the typical calcareous soil in Ningxia as material,exploring the immobilization ability of it on heavy metallic lead was exploried through the adsorption-desorption experiment. The results showed that the average adsorption rate of sierozem on heavy metal lead was 89.78%, and aeolian sandy soil was 80.29%,which indicated that the adsorption capacity of former on heavy metallic lead was stronger than latter. The contribution rate of organic matter on adsorption of lead in two kinds of soil (sierozem was 8.31%, and aeolian sandy soil was 7.87%) were less than the contribution rate of calcium carbonate (sierozem was 17.21%, and sand soil was 11.96%).Compared with the organic matter, the effect of calcium carbonate on adsorption heavy metallic lead in calcareous soil was greater.
Key words:calcium carbonate;soil;immobilization;heavy metal lead
目前,土壤重金屬污染已成為備受關注的全球性環境問題之一。鉛是土壤中一種重要的重金屬污染物,近年來有研究表明,土壤鉛的來源途徑較多。交通廢氣是道路兩側土壤鉛污染的重要來源[1]。垃圾、污泥的施用、污水灌溉[2,3]以及長期施用砷酸鉛殺蟲劑導致土壤受到一定程度的鉛污染;城市和工業區排放的廢氣是土壤鉛污染的另一重要來源。
近年來有關土壤重金屬鉛污染的研究較多[4-6],但是關于西部地區特別是寧夏地區石灰性土壤對重金屬鉛的固持以及石灰性土壤中碳酸鈣對土壤固持重金屬鉛的作用研究較少。因此本研究選用寧夏境內兩種性質不同的石灰性土壤為研究對象,探討石灰性土壤對重金屬鉛的固持能力,同時對碳酸鈣影響土壤固持重金屬鉛的作用加以初步探討,以期為石灰性土壤承載外源重金屬污染物的能力研究提供理論依據。……