二氯均三嗪反應(yīng)型紫外線吸收劑的合成與應(yīng)用

摘 要： 為解決C.I.活性紅24∶1染色棉織物在日光照射下容易褪變色以及市場(chǎng)上缺乏對(duì)棉織物具有耐久反應(yīng)性整理光穩(wěn)定化助劑的問(wèn)題，在苯并三唑紫外線吸收劑結(jié)構(gòu)中引入二氯均三嗪活性基和磺酸基，設(shè)計(jì)開(kāi)發(fā)了一種兼具優(yōu)良水溶性和反應(yīng)性且在合成過(guò)程中無(wú)需使用催化劑的新型紫外線吸收劑R1，并通過(guò)質(zhì)譜、紅外光譜、紫外-可見(jiàn)吸收光譜、核磁共振氫譜對(duì)產(chǎn)物分子結(jié)構(gòu)進(jìn)行表征；將R1分別應(yīng)用于未染色棉織物和C.I.活性紅24∶1染色棉織物，測(cè)試了固著率、UPF值、光致褪色率、耐光色牢度與耐洗性。結(jié)果表明：R1在未染色棉織物上的固著率達(dá)到85.47%，UPF值為118.97，染色織物表現(xiàn)出優(yōu)異的防紫外線透過(guò)能力；R1在染色棉織物上的固著率為65.41%，光致褪色率降低了5.07%；耐光色牢度提升了1.0級(jí)，皂洗10次后，UPF損失率降低不超過(guò)3.20%。反應(yīng)性紫外線吸收劑R1與棉織物反應(yīng)機(jī)理與活性染料相近，將R1整理到棉織物及染色制品上，對(duì)提升棉織物防紫外線性能、染色棉織物耐光性能以及耐久性具有較好的應(yīng)用價(jià)值。

關(guān)鍵詞：活性染料；反應(yīng)性紫外線吸收劑；耐光色牢度；二氯均三嗪；水溶性

中圖分類(lèi)號(hào)：TS193.22

文獻(xiàn)標(biāo)志碼：A

文章編號(hào)：1673-3851 （2025） 03-0221-08

引文格式：田濤，戚棟明，崔志華. 二氯均三嗪反應(yīng)型紫外線吸收劑的合成與應(yīng)用［J］. 浙江理工大學(xué)學(xué)報(bào)（自然科學(xué)），2025，53（2）：221-228.

Reference Format： TIAN Tao，QI Dongming，CUI Zhihua. Synthesis and application of dichlorometriazine reactive ultraviolet absorbers［J］. Journal of Zhejiang Sci-Tech University，2025，53（2）：221-228.

Synthesis and application of dichlorometriazine reactive ultraviolet absorbers

TIAN Tao¹， QI Dongming^1，2， CUI Zhihua^1，2

（1.College of Textile Science and Engineering （International Institute of Silk）， Zhejiang Sci-Tech University， Hangzhou 310018， China; 2.Innovation Center of Advanced Textile Technology （Jianhu Laboratory）， Shaoxing 312030， China）

Abstract：To solve the problem that C.I. reactive red 24∶1 dyed cotton fabrics are easy to fade under sunlight and that the market lacks of light stabilization additives with durable reactivity for cotton fabrics， dichloromistriazine active group and sulfonic acid group were introduced into the structure of benzotriazole UV absorbers. A new UV absorbent R1 with excellent water solubility and reactivity was designed and developed without the use of catalysts in the synthesis process， and the molecular structure of the product was characterized by mass spectrometry， infrared spectroscopy， UV-vis absorption spectroscopy and hydrogen NMR spectroscopy. R1 was applied to an undyed cotton fabric and C.I. reactive red 24∶1 dyed cotton fabric， and the fixing rate， UPF value， photofading rate， color fastness to light and washable ability were tested. The results showed that the fixed rate of R1 on the undyed cotton fabric reached 85.47%， the UPF value was 118.97， and the dyed cotton fabric showed excellent anti-ultraviolet transmission ability. The fixation rate of R1 on the dyed cotton fabric was 65.41%， and the photofading rate was reduced by 5.07%. The color fastness to light was increased by 1.0 level， and the UPF loss rate was reduced by no more than 3.20% after soaping for 10 times. The reaction mechanism of the reactive UV absorbent R1 with cotton fabrics is similar to that of reactive dyes. When R1 is finished on cotton fabrics and dyed products， it has a good application value to improve the UV resistance of cotton fabrics， and light resistance and durability of dyed cotton fabrics.

Key words：reactive dye; reactive ultraviolet absorber; color fastness to light; dichlorotriazine; water soluble

0 引 言

在棉織物印染中，含H酸結(jié)構(gòu)的偶氮型染料是紅色染料的主要發(fā)色體類(lèi)型；相較于其他原色染料，含H酸結(jié)構(gòu)的紅色偶氮染料染色織物通常表現(xiàn)出較低的耐光色牢度^［1］。……