Nitrogen doping/infusion of 650 MHz cavities for CEPC

Peng Sha·Jian-Kui Hao ·Wei-Min Pan ·Lin Lin ·Hong-Juan Zheng·Xin-Ying Zhang · Fang Wang · Ji-Yuan Zhai · Zheng-Hui Mi ·Fei-Si He· Shu Chen · Bai-Qi Liu · Zhi-Tao Yang · Chao Dong·Zhong-Quan Li

Abstract The nitrogen doping/infusion of 650 MHz cavities for the circular electron positron collider (CEPC) is investigated in this study.Two 650 MHz 1-cell cavities are first treated via buffered chemical polishing (BCP), followed by nitrogen doping. A ‘‘2/6’’ condition is adopted,similar to that for 1.3 GHz cavities of Linear Coherent Light Source II. The quality factor of both cavities improved to 7 × 1010 in low fields, i.e., higher than that obtained from the baseline test. One 650 MHz two-cell cavity is nitrogen infused at 165 °C for 48 h with a BCP surface base. The intrinsic quality factor (Q0) reached 6 × 1010 at 22 MV/m in the vertical test,and the maximum gradient is 25 MV/m, which exceeds the specification of the CEPC (4 × 1010 at 22 MV/m).

Keywords Superconducting radio frequency cavity ·Nitrogen doping · Nitrogen infusion · Quality factor ·Accelerating gradient

1 Introduction

Currently, superconducting radio frequency (SRF) cavities with a high quality factor (Q) are adopted in large accelerators worldwide [1, 2]. The Linear Coherent Light Source II (LCLS-II) in America uses a specific condition for nitrogen doping to increase Q0of 1.3 GHz 9-cell cavities.The average Q0of 280 nitrogen-doped 9-cell cavities reached 3.1 × 1010at 16 MV/m, which exceeded the specification of 2.7 × 1010. Owing to the excellent results of nitrogen doping,the LCLS-II High Energy program has continued to adopt nitrogen-doped cavities [3], which can be operated at 20.8 MV/m with Q0of 2.7 × 1010.In China,the construction of the Shanghai high repetition rate XFEL and extreme light facility(SHINE)began in April 2018,for which six hundred 1.3-GHz 9-cell cavities were required to obtain an 8 GeV electron beam. Moreover, the nitrogen doping of 1.3 GHz cavities was conducted in several institutes including the Peking University in China [4–6],and preliminary improvement was observed.

The circular electron positron collider(CEPC)is a highenergy collider at the Higgs factory that can operate in the W and Z modes [7]. The SRF system of the CEPC is extremely challenging because of the associated wide beam energy and current [8]. Two hundred and forty 650 MHz two-cell cavities exist in the collider, and ninety-six 1.3 GHz nine-cell cavities exist in the booster of the CEPC tunnel,which is located 100 m underground.The 650 MHz two-cell cavity will be operated in continuous wave mode with high Q, rendering the cryogenics system economical.The Q0was 4 × 1010at an accelerating gradient (Eacc) of 22 MV/m for the vertical acceptance test, and 1.5 × 1010at 19.7 MV/m for the operation [9]. This specification is critical for the SRF cavity of a circular collider, which has a more constrained environment than linacs (such as LCLS-II and SHINE).

Compared with the nitrogen doping/infusion of 1.3 GHz cavities, that of 650 MHz cavities are investigated less.Nitrogen doping of 650 MHz cavities was conducted at Fermi National Accelerator Laboratory (FNAL) [10]; it reached ～7 × 1010at 22 MV/m and recorded the highest Q worldwide. Nitrogen doping/infusion of 650 MHz cavities for the CEPC was conducted in collaboration with the Institute of High Energy Physics and Peking University.Nitrogen doping/infusion studies worldwide are primarily based on electro-polishing (EP), which can achieve a higher Eaccthan BCP. However, EP facilities are complicated and expensive, and EP conditions for 650 MHz cavities does not exist China. By contrast, BCP is considerably simpler and more convenient process than EP.Therefore, nitrogen doping/infusion based on BCP has been adopted and proven to be effective. Two 650 MHz one-cell cavities received nitrogen doping, and one 650 MHz two-cell cavity received nitrogen infusion. The nitrogen doping/infusion treatment and vertical test of 650 MHz superconducting cavities are presented herein.

2 Nitrogen doping of 650 MHz 1-cell cavities

In this study,nitrogen doping was conducted on two 650 MHz 1-cell cavities(650S1,650S2)made of fine-grain Nb.The primary parameters of the Nb used are listed in Table 1.

BCP was performed prior to nitrogen doping/infusion.The polishing was performed at the vertical BCP facility of Ningxia Orient Superconductor Technology Co., Ltd.(OSTEC), as shown in Fig. 1, which has been used for all types of SRF cavities. Both cavities received bulk BCP(150 μm), annealing at 750 °C for 3 h, and light BCP (30 μm). Subsequently, they were assembled in a clean room and subjected to low-temperature baking(120°C for 48 h).The vertical test results (baseline) of the two cavities are shown in Fig. 2. The maximum gradients of 650S1 and 650S2 reached 19.3 and 24.7 MV/m, respectively. Field emission, which might have resulted from contamination during the process, was observed at low fields in both cavities.

Table 1 Primary parameters of fine-grain niobium

After performing the vertical test on the BCP baseline,both cavities received another light BCP (30 μm) to eliminate contamination on the inner surface. The two cavities were nitrogen doped based on a ‘‘2/6’’ recipe,similar to that for the 1.3 GHz cavity of LCLS-II.First,the furnace was pumped until the pressure was less than 2 × 10–4Pa. Second, the furnace was heated by ramping its temperature to 800 °C for 3 h. Third, the furnace was maintained at 800 °C for 3 h for annealing. Finally,nitrogen gas was injected into the furnace for 2 min at ～3.5 Pa,followed by annealing at 800°C for 6 min.Finally,the furnace was cooled to ～50 °C under vacuum.

Fig. 1 (Color online) Setup for BCP of 650 MHz 1-cell cavity

Fig.2 (Color online)Vertical test results of 650S1 and 650S2(at 2.0 K)

Table 2 Primary parameters of 650 MHz 2-cell cavity

Because it is extremely difficult to achieve uniform removal via BCP, neither cavity underwent etching after nitrogen doping.The vertical test results at 2.0 K are shown in Fig.2.The Q0of both cavities exceeded 7 × 1010at low fields, which was higher than that obtained via the BCP baseline test. The Q-slope of 650S1 was evident above 10 MV/m;cavities 650S1 and 650S2 quenched at 16.6 and 8.8 MV/m, respectively. To remove the niobium nitride phase layer, the inner surface of the cavity after nitrogen doping must be removed lightly,and this is generally achieved via EP. Because no EP device exists, it is more suitable to improve the Q and Eaccof 650 MHz cavities via nitrogen infusion, which requires no EP of the inner surface after infusion [11].

3 Design of 650 MHz 2-cell cavity

Nitrogen infusion was performed on a 650 MHz 2-cell cavity. One 650 MHz 2-cell cavity was designed, manufactured, post-processed, nitrogen-infused, and tested.

The radio frequency (RF) design of a 650 MHz 2-cell cavity (650D1) was optimized to minimize Bpeak/Eaccand Epeak/Eacc.Meanwhile,the R/Q and cell coupling(k)should be maximized. The final RF parameters are presented in Table 2 [8].

The two important mechanical parameters of the 650 MHz 2-cell cavity were the Lorentz force detuning coefficient (KL) and frequency sensitivity to pressure (df/dp).The geometry and dimensions of the cavity are shown in Fig. 3. Two cavity wall thicknesses (3 and 4 mm) were compared, as summarized in Table 3. Finally, the 4 mm thickness was adopted because of the lower KLand df/dp.

4 BCP baseline test of 650 MHz 2-cell cavity

The 650 MHz two-cell cavity (650D1) was manufactured with fine-grain Nb, same as the 650 MHz one-cell cavity. Before nitrogen infusion, the cavity received bulk BCP(200 μm),annealing at 800°C for 3 h,and light BCP(30 μm);subsequently,it was assembled in a clean room.A vertical test was performed after these treatments,as shown in Fig. 4. The vertical test system comprised double magnetic shields, and the residual magnetic field around the cavity was less than 5 mGs. No compensation coils were used during the vertical test.Fast cooling was performed at a speed of ～5 K/min.The vertical test results of the BCP baseline at 2.0 K are shown in Fig. 5. The Q0of 650D1 reached 3.3 × 1010at 22 MV/m. Finally, the cavity quenched at 26.5 MV/m with a Q0of 1.4 × 1010. Strong multipacting occurred when the gradient was 11–18 MV/m; however, it can be avoided by increasing the input power. The simulation shows that multipacting can occur between 8 and 20 MV/m, which is consistent with the vertical test[9].The radiation resulting from field emission began to increase at 18.8 MV/m, indicating contamination on the inner surface of the cavity.

Fig.3 (Color online)Geometry and dimensions of 650 MHz 2-cell cavity

Table 3 Mechanical parameters of 650 MHz 2-cell cavity

5 Nitrogen infusion of 650 MHz 2-cell cavity

The 650 MHz two-cell cavity(650D1) received another light BCP (30 μm) and high-pressure rinsing (HPR) to remove possible contamination and reset the inner surface after the BCP baseline test. Subsequently, the cavity was transferred to a furnace for nitrogen infusion [12]. All six flanges were covered with clean Nb foil to avoid contamination and dust during nitrogen infusion,as shown in Fig.6.

The ‘‘165 °C 48 h’’ condition, which may achieve a higher Q than the‘‘120°C 48 h’’condition,was adopted in nitrogen infusion [11]. The pressure and temperature during nitrogen infusion are shown in Fig.7.First,the furnace was heated by ramping the temperature to 800 °C and maintaining it at that temperature for 3 h for annealing.Second, the furnace was cooled to 165 °C and maintained for half a minute.Third,nitrogen gas was injected into the furnace for 48 h at ～3.5 Pa. Finally, the furnace was cooled to ～50 °C under vacuum.

The inner surface of the nitrogen-infused 650D1 was analyzed using a new inspection camera. A typical image of the equator is shown in Fig. 8a; it is considerably rougher compared with that observed after EP,as shown in Fig. 8b. No defects were observed on the entire inner surface of the 650D1.

After nitrogen infusion,650D1 underwent HPR and was assembled in a clean room for vertical testing.The vertical test results of 650D1 at 2.0 K are shown in Fig. 9. In the first vertical test,Q0reached 7.2 × 1010at 9 MV/m,which was 40% higher than the BCP baseline. However, Q0decreased rapidly above 9 MV/m because of strong field emissions induced by contamination during clean room assembly and transfer. Finally, the gradient reached 13.6 MV/m with a Q0of 5.2 × 109. To eliminate the field emission, 650D1 was subjected to HPR and re-assembled,followed by a second vertical test. At this time, the cavity achieved a higher Q0than the BCP baseline over the entire range of gradient. The Q0was 6 × 1010at 22 MV/m,which exceeded the vertical test specification (4 × 1010at 22 MV/m) for the CEPC. This result is similar to that recorded by FNAL (7 × 1010at 22 MV/m), which was based on EP.Therefore,nitrogen infusion based on BCP is applicable in medium fields (～20 MV/m). No field emission was observed until the quench gradient reached 25 MV/m with a Q0of 3.3 × 1010. Multipacting was avoided by increasing the input power. To eliminate the multipacting effect,a new 650 MHz 2-cell cavity has been designed and proven to be effective [13].

Fig. 4 (Color online) Vertical test of 650 MHz 2-cell cavity

Fig. 5 (Color online) Vertical test results of BCP baseline (at 2.0 K)

Fig. 6 (Color online) Nitrogen infusion of 650 MHz 2-cell cavity

Fig. 7 (Color online) Temperature and pressure during nitrogen infusion

Fig. 8 (Color online)Inspection of cavity equator.(a) 650D1 (nitrogen infused);(b) 1.3 GHz cavity (after EP)

Fig. 9 (Color online) Vertical test results of 650 D1 (at 2.0 K)

6 Conclusion

Nitrogen doping and infusion studies were conducted on 650 MHz superconducting cavities for CEPC.Owing to the lack of EP conditions for the 650 MHz cavity and to identify other possible methods, a BCP surface baseline was adopted, and no BCP or EP was conducted after nitrogen doping/infusion.

Owing to nitrogen doping,the Q0of the 650 MHz 1-cell cavity exceeded 7 × 1010at low fields, which was higher than the 5–6 × 1010obtained via the BCP baseline test.The 650 MHz 2-cell cavity attained a Q0of 6 × 1010at 22 MV/m after nitrogen infusion based on the‘‘165°C 48 h’’condition.It was evident that nitrogen infusion increased Q0.Both Q0and Eaccexceeded the specifications of the CEPC.

Author contributionsAll authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Peng Sha, Jian-Kui Hao and Ji-Yuan Zhai. The first draft of the manuscript was written by Peng Sha and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.