手性超分子納米結(jié)構(gòu)的調(diào)控及其相關(guān)功能研究報告

劉鳴華++陳鵬磊

摘 要：研究包括：（1）環(huán)己二胺誘導(dǎo)下TPPS組裝體螺旋結(jié)構(gòu)的可控構(gòu)筑及其超分子手性的控制；（2）金屬離子誘導(dǎo)的超分子手性翻轉(zhuǎn)和調(diào)控：智能超分子水凝膠；（3）凝膠調(diào)控的拓撲化學反應(yīng)及其超分子手性；（4）超分子手性的傳遞及基于動態(tài)共價鍵的超過分子手性光學開關(guān)。

關(guān)鍵詞：手性超分子納米結(jié)構(gòu) 手性控制 有機凝膠 手性翻轉(zhuǎn) 手性開關(guān) 組裝 功能材料

A General Scientific Report for Chiral Supramolecular Nanoassemblies： Controlled Structure and Chirality， and Related Advanced Functions

Liu Minghua Chen Penglei

（Institute of Chemistry， Chinese Academy of Sciences）

Abstract：In this general scientific report， we summarized our recent progress on chiral supramolecular nanoassemblies： controlled structure and chirality， and related advanced functions， which are obtained since the inauguration of the project. The main issues include the following items： （1）self-assembly of TPPS in organic solvents： from nanofibers to mirror imaged chiral nanorods； （2）a metal ion triggered shrinkable supramolecular hydrogel and controlled release by an amphiphilic peptide dendron； （3）organogelation-controlled topochemical [2+2] cycloaddition and morphological changes： from nanofiber to peculiar coaxial hollow toruloid-like nanostructures； （4）a chiroptical switch based on supramolecular chirality transfer through alkyl chain entanglement and dynamic covalent bonding. Focusing on the issues that we originally assigned in the Plan of the Project， these obtained achievements during 2013 provide us with solid grounds for the performance the future work， which will be carried out in the next year. On the basis of these important result， we believe that advanced materials of tunable functions in terms of multi-level chirality might be developed in our further work.

Key Words：Chiral supramolecular nanoassemblies； Controlled chirality； Organic gel； Chirality conversion； Chiroptical switch； Assembly； Functional materials